Muguet

        You may not recognise the name immediately unless you are a French speaker Muguet is Lily of  the Valley to us English speakers.

        Why didn't we just say Lily of the Valley then? - this is because most of the Lily family are large flowers with no odour at all, and the remainder do not display a common odour characteristic. We have found that when the term Lily of the Valley is used then streams of questions arise about the other Lilies - fragrance wise, there is no connection.
 

Muguet Flowers
 
        Lily of the Valley is a Lily in a genus Convalallaria Majalis all of its own. It is a small creeping Lily about 12-18' tall with a pair of emerald green lance like leaves extending from the roots. Between this pair of leaves a single spike rises and leans to one side and from which tiny brilliant white dangling bells fall.

        The delicate sweet odour of Muguet has no equal. It is elegant and sophisticated but still lively and fresh, there is none of the heavyness associated with the narcotic florals. I can do no more justice to the fragrance of Muguet than John Lawrence, who wrote almost 300 years ago:

"the conval-lily is esteemed to have, of all others, the sweetest and most agreeable perfume; not offensive nor overbearing, even to those who are made uneasy with the perfumes of other sweet scented flowers"  The Flower Garden (1726) - 'Scented Flora of the World' - Roy Genders
        Now, like many beautiful things in nature the act of trying to capture, cage and analyse, all but destroy it. So too, with the natural aroma components of the Muguet. All attempts to date to produce an acceptable commercial extract have met with failure. There are no Muguet absolutes or essential oils to our knowledge available on the open market. So in re-producing the soul of the Muguet fragrance we must look elsewhere.

        Analysis of the chemical composition of Muguet reveals to us that the main components are the rose alcohols Citronellol, Geraniol, Nerol and their esters, Phenyl Ethyl Alcohol and Linalool, Indol, traces of cis-3-Hexenol and its esters . However, these materials simply give us a rosy odour base from which to work from and do not explain the the sophistication of the odour. Synthetics with no natural equivalents come into play here and it is Hydroxycitronellal that is traditionally the most representative of the Muguet odorants. In compounds we can frequently find up to 40% of Hydroxycitronellal. More recently developed aroma chemicals have added to the palette of the perfumer such as Lilial - Givaudan-Roure, Lyral - IFF, Dupical - Quest, Mayol - Firmenich. It is these materials that usually form the basic structure of the Muguet fragrance. The rose alcohols act as a combination of blenders/modifiers. Muguet flowers display a natural greeness which is frequently replicated using cis-3-Hexenol, cis-3-Hexenyl Benzoate and this greeness can be modified with Phenyl Acetaldehyde and traces of Galbanum notes.

        The fragrance can be blended and smoothed with the use of Linalool and Tepineol, the latter used carefully adds depth and power but overuse gives a lilac/pine character. Hedione, Helional, Cyclamen Aldehyde are useful blending agents for Muguet.

        Fixatives for Muguet include Indol which gives depth without undue sweetness. Traces of Civet Extract (a lot less than 1%) help to give a natural effect. Macro and polycyclic musks are useful. Lyral and Dupical both have excellent tenacity and can be increased to act as fixatives.
 
 

Muguet
.  
.............................................
%
Remarks - e.g. overdose effect
Basics   
Hydroxycitronellal
20-40
Synthetic grades easier to use .
Lyral
5-30 
 Long lasting
Lilial
5-25 
Aldehydic character 
Citronellol
5-20
rosy muguet note good body 
  .
Modifiers   
Rose -
 
 
Phenyl Ethyl Alcohol
5-25 
light rosy soft 
Geraniol 
1-5 
 metallic rose
.  
Green - 
 
 
cis-3-Hexenol
0.1-1
fresh cut grass green 
Phenyl Acetaldehyde 
Dimethyl Acetal (PADMA)
0.2-2
leafy green (harsh)
.
Blenders   
Linalool 
10-30 
blender fresh floral 
Terpineol 
1-5 
Lilac/Pine add depth
Helional 
0.1-3 
 light green sweet radiant
Cyclamen Aldehyde 
1-10 
 cool green Hydroxy. like
Phenyl Ethyl Alcohol
5-25
 soft rosy
  .
Fixatives   
Indol (Tip use as 10% solution)
0.1-0.5 
discolouration
Civet Extract/Civet Fleuressence  0.1-0.5
essential in traces (dirty fecal) 
.
Novel Effects  
Dupical
0.1-2
very strong Muguet note
Ethyl Methyl Phenyl Glycidate 
traces
strawberry for top note
Citronellal (the aldehyde of Citronellol)
traces
adds power but use sparingly
Benzyl Acetate
1-5
Increase depth and top note 
Phenyl Propyl Alcohol
1-3
Increase depth of greeness
Cinnamic Alcohol
1-5
Increase depth - lilac character
Nerolidol
1-10
Blender
Methyl Octine Carbonate 0.05-0.1
Violet greeness
Nerol
1-5
Rose-citrus body - magnolia twist
Rose de Mai Absolute
0.1-3
"Natural" effect
Coriander Oil
0.1-1
Modifier for Linalool blending
cis-3-Hexenyl Benzoate
0.5-2
Blender for green notes
.NB. These recommendations are for guidance and hints - do not be afraid to try as many different materials as possible
 
 
 
 
 
Muguet Formulation Example
 Hydroxycitronellal 
 Citronellol 
 Lyral 
 Lilial 
 Phenyl Ethyl Alcohol 
 Linalool 
 Terpineol 
 Cyclamen Aldeyde 
 cis-3-Hexenol 
 Helional 
 Indol 
 Civet Fleuressence 
 Phenyl Acetaldehyde Dimethyl Acetal 
 Rose de Mai Absolute
40.00 
10.00 
5.00 
8.00 
18.00 
12.00 
3.00 
1.00 
0.30 
1.70 
0.20 
0.10 
0.50 
0.20 
.
100.00